Operator, including using Cloudflare, but there is strong reason to believe the operator is still in Vietnam content is uploaded using cyberlockers from numerous email accounts originating from Can Tho University of Medicine and Pharmacy". In October 2017, the MPAA listed 123Movies (and GoStream.is) in its Online Notorious Markets overview to the Office of the United States Trade Representative, stating that while the site was technically hosted from Ukraine that: "The site takes numerous steps to hide the identity of the In March 2017, TorrentFreak reported that the US ambassador to Vietnam, Ted Osius, had been in talks with the local Minister of Information and Communications, Truong Minh Tuan, about shutting down illegal video streaming sites operating from Vietnam, and listed 123movies as one specific site. In December 2017, the creators of 123movies launched another streaming site dedicated to anime, named AnimeHub.to, which remained online for months after 123Movies's shutdown. During its existence and shutdown period, the site was covered by TorrentFreak regarding its features, uptime/downtime, shutdown, and reasons for shutdown. The video hosters and players it used included Openload, Streamango, and M圜loud. ġ23Movies included HD, HD-RIP, Blu-ray and camera qualities of films. In October 2016, Business Insider reported that 123movies.to was the "most-used pirate website" in the United Kingdom. 123movies.to had 9.26 million worldwide unique visitors in August 2016 according to SimilarWeb data". In October 2016, the MPAA listed 123Movies in its Online Notorious Markets overview to the Office of the United States Trade Representative (USTR), stating that: "The site has a global Alexa rank of 559 and a local rank of 386 in the U.S. It was changed to gostream.is, and then to memovies.to, before changing to 123movieshub.to/is and remaining there until shutdown. The original name, and URL, was 123movies.to, which changed to other domains including 123movies.is before redirecting to gomovies.to and later gomovies.is. The site went through several name changes after being shut down from different domains sometimes the name appeared as "123Movies", and other times as "123movies".
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It was closed in March 2020 after a man was fatally stabbed on the platform and reopened hours afterwards. The Metro bus platform, a major entrance to the Pentagon, is used by multiple bus lines in the area every day. The Washington Metropolitan Area Transit Authority said trains and busses were bypassing their stops at the transit center due to the investigation. "We request that everyone stay away from the Metro rail entrance and bus platform area." Pat Milton and Andres Triay contributed to this report. that the lockdown was lifted and the facility reopened. The Pentagon spent more than an hour in lockdown Tuesday morning after reports of multiple shots fired at the Pentagon Transit Center. Corridor 2 and the Metro entrance remains closed. The Pentagon has lifted the lock down and has reopened. "The Pentagon has lifted the lock down and has reopened," the agency said on Twitter. The Pentagon Force Protection Agency announced just before 12:15 p.m. EST: The lockdown has been lifted according to a tweet from the Pentagon Force Protection Agency, though two corridors remain closed due to an active crime scene investigation ongoing. One other officer was injured and sent to hospital. The Pentagon Force Protection Agency, which oversees the. Mark Warner (D-Va. The Pentagon would not confirm the officer had been killed until many hours after the episode, despite multiple reports and apparent confirmation by several lawmakers, including Sen. The gunman was shot by a Pentagon police officer and did not get inside the Pentagon building, the agency's official told POLITICO. CNN A police officer died Tuesday after shots were fired outside the Pentagon building, according to three law enforcement sources. The lockdown was lifted roughly an hour and a half later, after the Pentagon police secured the scene. The Pentagon Force Protection Agency, which sent out a lockdown alert following the "shooting event," said at the noon time that the facility reopened and the "scene of the incident is secure" though remains an active crime scene. 3 (Xinhua) - The Pentagon lifted the lockdown roughly an hour and a half after multiple gunshots were fired near the Metro bus platform outside the building on Tuesday morning. The Pentagon lifted the lockdown roughly an hour and a half after multiple gunshots were fired near the Metro bus platform outside the building on Tuesday morning. 3, 2021 shows the Pentagon in Arlington, Virginia, the United States. The lockdown has since been lifted, the agency announced later Tuesday, tweeting: The Pentagon has lifted the lock down and has reopened. This offering sales code from Cdkeys is issued by Cdkeys. You can contact with this publisher at to get confirmation about this Gorogoa Switch offering sales codes. 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Homebrew is similar to Macports and provides packages (aka formulas) to install, either by compiling them from source or by using pre-made binaries. Port file pointed to the current stable releaseĪnd we have reports from people who've built GIMP To install gimp using Macports, you simply do sudo port install gimp once you have Macports installed. The installer allows you to choose from a large directory of packages. Widely used FLOSS projects, though we won't list projectsĪn easy way to compile and install GIMP and other great Free software on your Mac is by using Macports. We only list some of these package systems here because they are Therefore you should report issues to the packagersįirst, before reporting to the GIMP team. Third party packages are not officially supported by the GIMP Previous installers for macOS/OSX can be found here:. Just open the downloaded DMG and drag and drop GIMP into your "Applications" folder. 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This row concludes with the noble gas argon, which has the electron configuration 3 s 2 3 p 6, corresponding to a filled valence shell.ĭraw an orbital diagram and use it to derive the electron configuration of phosphorus, Z = 15. We would therefore predict that sodium and lithium have very similar chemistry, which is indeed the case.Īs we continue to build the eight elements of period 3, the 3 s and 3 p orbitals are filled, one electron at a time. It is readily apparent that both sodium and lithium have one s electron in their valence shell. Using this notation to compare the electron configurations of sodium and lithium, we have: Sodium The simplified notation allows us to see the valence-electron configuration more easily. This means that the chemistry of an atom depends mostly on the electrons in its outermost shell, those with the highest n-value, which are called the valence electrons. We will revisit this definition of core electrons later on for transition metals. Thus, the core electrons are those in the atomic orbitals with n < 3, namely those in the 1s, 2s and 2p orbitals. For example, in the sodium atom the highest n-value is 3. For the representative elements (columns 1, 2, and 13-18 of the Periodic Table), the core electrons are all electrons with an n-value lower than the maximum n-value in the electron configuration. For example, represents the 1 s 2 2 s 2 2 p 6 electron configuration of neon ( Z = 10), so the electron configuration of sodium, with Z = 11, which is 1 s 2 2 s 2 2 p 6 3 s 1, is written as 3 s 1Įlectrons in filled inner orbitals are closer to the nucleus and more tightly bound to it, and therefore they are rarely involved in chemical reactions. In practice, chemists simplify the notation by using a bracketed noble gas symbol to represent the configuration of the noble gas from the preceding row because all the orbitals in a noble gas are filled. Figure 2.1.1 tells us that the next lowest energy orbital is 2 s, so the orbital diagram for lithium isĪs we continue through the periodic table in this way, writing the electron configurations of larger and larger atoms, it becomes tedious to keep copying the configurations of the filled inner subshells. We know that the 1 s orbital can hold two of the electrons with their spins paired. The next element is lithium, with Z = 3 and three electrons in the neutral atom. Otherwise, our configuration would violate the Pauli principle. Written as 1 s 2, where the superscript 2 implies the pairing of spins. The orbital diagram for the helium atom is therefore From the Pauli exclusion principle, we know that an orbital can contain two electrons with opposite spin, so we place the second electron in the same orbital as the first but pointing down, so that the electrons are paired. We place one electron in the orbital that is lowest in energy, the 1 s orbital. Unless there is a reason to show the empty higher energy orbitals, these are often omitted in an orbital diagram: Figure 2.1.1), and the electron configuration is written as 1 s 1 and read as “one-s-one.”Ī neutral helium atom, with an atomic number of 2 ( Z = 2), has two electrons. Some authors express the orbital diagram horizontally (removing the implicit energy axis and the colon symbol): Here is a schematic orbital diagram for a hydrogen atom in its ground state: A filled orbital is indicated by ↑↓, in which the electron spins are said to be paired. We use the orbital energy diagram of Figure 2.1.1, recognizing that each orbital can hold two electrons, one with spin up ↑, corresponding to m s = +½, which is arbitrarily written first, and one with spin down ↓, corresponding to m s = −½. First we determine the number of electrons in the atom then we add electrons one at a time to the lowest-energy orbital available without violating the Pauli principle. 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